Connectivity of the Hexagonal, Cubic, and Isotropic Phases of the C12EO6/H2O Lyotropic Mixture Investigated by Tracer Diffusion and X-ray Scattering - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Physical Chemistry B Année : 2001

Connectivity of the Hexagonal, Cubic, and Isotropic Phases of the C12EO6/H2O Lyotropic Mixture Investigated by Tracer Diffusion and X-ray Scattering

Doru Constantin
Patrick Davidson
Paul Sotta

Résumé

The connectivity of the hydrophobic medium in the nonionic binary system C12EO6/H2O is studied by monitoring the diffusion constants of tracer molecules at the transition between the hexagonal mesophase and the fluid isotropic phase. The increase in the transverse diffusion coefficient on approaching the isotropic phase reveals the proliferation of bridgelike defects connecting the surfactant cylinders. This suggests that the isotropic phase has a highly connected structure. Indeed, we find similar diffusion coefficients in the isotropic and cubic bicontinuous phases. The temperature dependence of the lattice parameter in the hexagonal phase confirms the change in connectivity close to the hexagonal-isotropic transition. Finally, an X-ray investigation of the isotropic phase shows that its structure is locally similar to that of the hexagonal phase.
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Dates et versions

hal-00015623 , version 1 (12-12-2005)

Identifiants

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Doru Constantin, Patrick Oswald, Marianne Impéror-Clerc, Patrick Davidson, Paul Sotta. Connectivity of the Hexagonal, Cubic, and Isotropic Phases of the C12EO6/H2O Lyotropic Mixture Investigated by Tracer Diffusion and X-ray Scattering. Journal of Physical Chemistry B, 2001, 105, pp.668. ⟨10.1021/jp002672h⟩. ⟨hal-00015623⟩
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